Source Journal of Chinese Scientific and Technical Papers
Included as T2 Level in the High-Quality Science and Technology Journals in the Field of Architectural Science
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Volume 56 Issue 1
Jan.  2026
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Article Contents
HAN Yudong, LIANG Ying, LI Wei, YUE Qingrui, JIANG Chongwen, MAO Xin. Review on Epoxy Resin and Its Composite Engineering Materials[J]. INDUSTRIAL CONSTRUCTION, 2026, 56(1): 151-167. doi: 10.3724/j.gyjzG25102802
Citation: HAN Yudong, LIANG Ying, LI Wei, YUE Qingrui, JIANG Chongwen, MAO Xin. Review on Epoxy Resin and Its Composite Engineering Materials[J]. INDUSTRIAL CONSTRUCTION, 2026, 56(1): 151-167. doi: 10.3724/j.gyjzG25102802

Review on Epoxy Resin and Its Composite Engineering Materials

doi: 10.3724/j.gyjzG25102802
  • Received Date: 2025-10-28
    Available Online: 2026-02-26
  • Publish Date: 2026-01-22
  • Epoxy resin is an important type of thermosetting resin, featuring excellent mechanical, adhesive, corrosion resistance, crack resistance, and fatigue resistance properties, and is widely used in engineering. Regarding the development, research, and application of epoxy-based engineering materials, this paper first summarizes its three-stage development process, then elaborates on the curing reaction mechanism and key performance control techniques of epoxy materials, and proposes solutions to the common brittleness problems. It classifies the materials based on their working state and functions during construction. It also provides a detailed introduction to various commonly used epoxy-based engineering materials in current engineering, analyzes the current research deficiencies and technical bottlenecks, and focuses on the new trends and demands of “high reinforcement, functionalization, high adaptability, and greenness”, proposing new development directions for epoxy-based engineering materials. Finally, it sorts out the product standards, performance testing methods, and engineering application standards of epoxy-based engineering materials, and looks forward to their future research and application development prospects, and puts forward several suggestions in combination with new engineering demands.
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  • [1]
    PRILESCHAJEW N. Oxydation ungesättigter verbindungen mittels organischer superoxyde[J]. Berichte der Deutschen Chemischen Gesellschaft,1909,42(4):4811-4815.
    [2]
    MAY C. Epoxy resins:chemistry and technology[M]. 2nd edition. Boca Raton:Routledge,2018.
    [3]
    朱红军,王建军. 环氧树脂的生产、消费及国内外生产技术进展[J]. 中国氯碱,2002(9):23-24.
    [4]
    MI X,LIANG N,XU H,et al. Toughness and its mechanisms in epoxy resins[J]. Progress in Materials Science,2022,130:100977.
    [5]
    范学忠,张蓓. 环氧树脂产业发展现状及趋势[J]. 中国石油和化工经济分析,2014(5):56-58.
    [6]
    陈平,王德中. 环氧树脂及其应用[M]. 北京:化学工业出版社,2004.
    [7]
    张玉龙,唐磊. 环氧胶黏剂[M]. 北京:化学工业出版社,2010.
    [8]
    THOMAS R,DURIX S,SINTUREL C,et al. Cure kinetics,morphology,and miscibility of modified DGEBA-based epoxy resin-effects of a liquid rubber inclusion[J]. Polymer,2007,48(6):1695-1710.
    [9]
    刘凤丹. 柔性链段和功能化石墨烯改性环氧树脂的研究[D]. 长沙:湖南大学,2014.
    [10]
    罗涛. 邻苯二甲腈改性环氧树脂及其碳纤维增强复合材料的性能研究[D]. 无锡:江南大学,2025.
    [11]
    JIN F L,LI X,PARK S J. Synthesis and application of epoxy resins:A review[J]. Journal of Industrial and Engineering Chemistry,2015,29:1-11.
    [12]
    TARAFDAR A. UV-induced frontal polymerization for optimized in-situ curing of epoxy resin for excellent tensile and flexural properties[J]. Composites Communications,2024,46:101832.
    [13]
    雷运波,蒋懋,陈辉国,等. 微波固化环氧树脂混凝土路面抢修材料的力学性能[J]. 建筑材料学报,2013(4):599-602.
    [14]
    岳丹. 端羧基丁腈橡胶改性环氧树脂的结构与性能[D]. 成都:电子科技大学,2016.
    [15]
    赵玉春,刘浩,李智慧,等. 环氧树脂中温潜伏型固化剂研究进展[J]. 热固性树脂,2019,34(4):66-70.
    [16]
    王志远,陈刚,魏化震,等. 潜伏性改性咪唑低温固化剂/环氧树脂体系的性能[J]. 工程塑料应用,2023,51(8):154-159.
    [17]
    陈青,宫大军,魏伯荣,等. 端羧基丁腈橡胶改性环氧树脂的研究[J]. 绝缘材料,2011,44(2):30-33.
    [18]
    MI X,LIANG N,XU H,et al. Toughness and its mechanisms in epoxy resins[J]. Progress in Materials Science,2022,130:100977.
    [19]
    WISE C W,COOK W D,GOODWIN A A. CTBN rubber phase precipitation in model epoxy resins[J]. Polymer,2000,41(12):4625-4633.
    [20]
    CHIKHI N,FELLAHI S,BAKAR M. Modification of epoxy resin using reactive liquid(ATBN)rubber[J]. European Polymer Journal,2002,38(2):251-264.
    [21]
    DONG L,ZHOU W,SUI X,et al. A carboxyl-terminated polybutadiene liquid rubber modified epoxy resin with enhanced toughness and excellent electrical properties[J]. Journal of Electronic Materials,2016,45(7):3776-3785.
    [22]
    SINH L H,SON B T,TRUNG N N,et al. Improvements in thermal,mechanical,and dielectric properties of epoxy resin by chemical modification with a novel amino-terminated liquid-crystalline copoly(ester amide)[J]. Reactive& Functional Polymers,2012,72(8):542-548.
    [23]
    BAGHERI R,MAROUF B T,PEARSON R A. Rubber-toughened epoxies:a critical review[J]. Polymer Reviews,2009,49(3):201-225.
    [24]
    高原. 环氧树脂/端羧基丁腈橡胶复合材料的制备及固化动力学研究[D]. 长春:长春工业大学,2018.
    [25]
    SHI J W,CAO W H,XU B L. Effect of liquid rubber modification on the bond behavior of externally bonded FRP laminate-concrete interface under dynamic loading[J]. Journal of Building Engineering,2020,32:101533.
    [26]
    曹璐. 环氧树脂增韧研究进展[J]. 中国胶粘剂,2019,28(5):49-52.
    [27]
    GHAMARPOOR R,JAMSHIDI M,MOHAMMADPOUR M. Achieving outstanding mechanical/bonding performances by epoxy nanocomposite as concrete–steel rebar adhesive using silane modification of nano SiO2[J]. Scientific Reports,2023,13(1):9157.
    [28]
    郑亚萍,郑国兵,陈超,等. 一种韧性固化剂的制备及其性能[J]. 高分子材料科学与工程,2014,30(4):162-167.
    [29]
    YI J,LI S,XIA J,et al. Preparation and properties of polyether aliphatic polymerized amide as a vegetable oil-based epoxy curing agent[J]. ACS Omega,2019,4(4):6238-6244.
    [30]
    谭延方,赵海鹏,赵亚奇,等. 新型增韧环氧树脂固化剂的合成及性能研究[J]. 中国胶粘剂,2022,31(4):21-27.
    [31]
    ZHANG P,KAN L,ZHANG X,et al. Supramolecularly toughened and elastic epoxy resins by grafting 2-ureido-4[1H]-pyrimidone moieties on the side chain[J]. European Polymer Journal,2019,116:126-133.
    [32]
    BAO Q,WANG B,LIU Y,et al. Epoxy resin flame retarded and toughened via flexible siloxane chain containing phosphaphenanthrene[J]. Polymer Degradation and Stability,2020,172:109055.
    [33]
    FRANCIS B,THOMAS S,JOSE J,et al. Hydroxyl terminated poly(ether ether ketone)with pendent methyl group toughened epoxy resin:miscibility,morphology and mechanical properties[J]. Polymer,2005,46(26):12372-12385.
    [34]
    YANG G,ZHENG B,YANG J P,et al. Preparation and cryogenic mechanical properties of epoxy resins modified by poly(ethersulfone)[J]. Journal of Polymer Science Part A:Polymer Chemistry,2008,46(2):612-624.
    [35]
    YAN C,SONG L,WANG H,et al. Preparation of reactive phenolphthalein poly(aryl ether ketone)for toughening epoxy resin:Synthesis,characterization,and performance evaluation[J]. Reactive and Functional Polymers,2024,199:105911.
    [36]
    许大玉. 基于纳米颗粒改性的环氧树脂胶粘剂力学性能研究[D]. 大连:大连理工大学,2022.
    [37]
    姜云,李波,亓帅,等. 预制构件拼接胶在南京长江第五大桥节段梁拼接密封防水工程中的应用与研究[J]. 中国建筑防水,2021(1):14-18.
    [38]
    KE L,ZHANG R,FENG Z,et al. Performance evolution of epoxy adhesive and CFRP-steel epoxy-bonded joints subjected to hygrothermal exposure[J]. Construction and Building Materials,2024,429:136445.
    [39]
    WANG W,ZHAO W,ZHANG J,et al. Epoxy-based grouting materials with super-low viscosities and improved toughness[J]. Construction and Building Materials,2021,267:121104.
    [40]
    KONG M,LIU C,TANG B,et al. Improved mechanical and thermal properties of trifunctional epoxy resins through controlling molecular networks by ionic liquids[J]. Industrial& Engineering Chemistry Research,2019,58(19):8080-8089.
    [41]
    LI X,WANG F,CAI X,et al. A porous IPN-structured polyurethane/epoxy grouting material with low viscosity,high strength and low volume shrinkage[J]. Construction and Building Materials,2024,449:138312.
    [42]
    李龙梓,彭先兵,孙静娴,等. 材料组份对高强环氧灌浆料性能影响研究[J]. 混凝土与水泥制品,2024(9):13-16.
    [43]
    陈肖寒,白杨,王志超,等. 低表面处理环氧防腐底漆的制备及其耐蚀性研究[J]. 中国腐蚀与防护学报,2023,43(5):1126-1132.
    [44]
    张治财,齐福刚,赵镍,等. 环氧树脂防腐涂料的研究进展及发展趋势[J]. 功能材料,2021,52(6):6069-6075.
    [45]
    ZHANG T,ZHANG T,HE Y,et al. Long-term atmospheric aging and corrosion of epoxy primer-coated aluminum alloy in coastal environments[J]. Coatings,2021,11(2):237.
    [46]
    杨喜丽,郑鸿芳,陈宙飞. 金刚砂耐磨地坪:CN105155818A[P]. 2015-12-16.
    [47]
    XIAN G,QI X,LI J,et al. Effect of particle size and content of Al2O3 on friction behavior and wear mechanism of epoxy resin composite[J]. Polymer Composites,2025,42(1):1-11.
    [48]
    尚守平,吕军在. 环氧树脂胶泥在混凝土抗渗试验中的应用[J]. 建筑结构,2016,46(2):26-29.
    [49]
    李志坚,邵亮. 环氧胶泥在三峡二期工程导流底孔缺陷修补中的应用[J]. 水利水电快报,2011,32(12):35-38.
    [50]
    孟雨辰,王彦辉,荆蓉,等. 碳纤维复合材料用环氧树脂体系研究进展[J]. 现代化工,2020,40(增刊1):75-78.
    [51]
    周桂鹏. 玻璃纤维增强复合材料(GFRP)在建筑结构中的应用综述[J]. 广州建筑,2024,52(6):117-120.
    [52]
    李彪,杨勇新,赵进阶,等. 结构工程用碳纤维复材筋力学性能影响因素试验研究[J]. 建筑结构,2020,50(2):72-75.
    [53]
    KIM Y J,HASSANI A. Stepped reinforced concrete beams retrofitted with carbon fiber-reinforced polymer sheets and ultra-high-performance concrete[J]. ACI Structural Journal,2023,120(2):91-104.
    [54]
    CAO S,JIANG T,SHI S,et al. Fabrication and compression properties of reinforced epoxy syntactic foam with basalt fiber[J]. Advances in Polymer Technology,2024,2024(1):9224136.
    [55]
    MA L,LIU H,WEN X,et al. Polyhydric SiO2 coating assistant to graft organophosphorus onto glass fabric for simultaneously improving flame retardancy and mechanical properties of epoxy resin composites[J]. Composites Part B:Engineering,2022,243:110176.
    [56]
    于钦萍,王炜. 阻燃可雕刻环氧灰浆的制备[J]. 绿色科技,2016(8):146-148.
    [57]
    WANG Z,JIANG B,LIU Y,et al. Three-dimensional printing of rigid-flexible ceramic-epoxy composites with excellent mechanical properties[J]. Materials,2025,18(7):1479.
    [58]
    曹登云,任银霞. 临海地区水下钢结构防腐技术试验研究[J]. 全面腐蚀控制,2024,38(11):176-179.
    [59]
    高浩,赵沈军,程庆超. 尼日利亚凯恩吉水电站溢洪道水下环氧快速修复技术[J]. 水利水电快报,2025,46(8):61-66.
    [60]
    LI G,WU Y,ZHANG P,et al. Interfacial study of steel joints prepared with a catechol-modified epoxy adhesive with enhanced bonding performance and durability[J]. Langmuir,2024,40(31):16549-16556.
    [61]
    WANG L,WANG J,QI Y,et al. Preparation of novel epoxy resins bearing phthalazinone moiety and their application as high-temperature adhesives[J]. Polymers,2018,10(7):708.
    [62]
    PENG Z,SUN Z,QIN Y,et al. Preparation and evaluation of the high-temperature-resistant epoxy resin with thermal expansion properties enables Z-axis reinforcement[J]. Composites Communications,2025,56:102372.
    [63]
    王先前,姚淑芳,高硕,等. 冬季低温预制节段改性拼接胶的制备与性能研究[J]. 粘接,2024,51(12):9-13.
    [64]
    李博洋,吴香国,张明熠,等. 负温下风电混塔拼接胶的抗流挂性能和可工作时间研究[J]. 混凝土与水泥制品,2024(10):23-26.
    [65]
    ZHANG X,SHI X,SHI Y,et al. Construction of interpenetrating networks structure in epoxy resin with both high modulus and high toughness and research on properties of polymers[J]. Journal of Applied Polymer Science,2025,142(25):e57061.
    [66]
    郭何云,王煦. 水性环氧树脂制备方法的研究进展[J]. 合成化学,2017,25(5):457-460.
    [67]
    孙国强,杨建军,陈春俊,等. 纳米改性水性环氧树脂防腐涂料的研究进展[J]. 现代化工,2022,42(4):33-38.
    [68]
    MAO X,HE Y,LI C,et al. Glycine–Ti3C2Tx hybrid material improves the electrochemical corrosion resistance of a water-borne epoxy coating[J]. Langmuir,2024,40(22):11817-11827.
    [69]
    郑木莲,范贤鹏,李洪印,等. 道路用水性环氧乳化沥青的研究进展[J]. 中国科技论文,2019,14(8):821-829.
    [70]
    YANG X,GUO L,XU X,et al. A fully bio-based epoxy vitrimer:self-healing,triple-shape memory and reprocessing triggered by dynamic covalent bond exchange[J]. Materials& Design,2020,186:108248.
    [71]
    REINHARDT N,BREITSAMETER J M,DRECHSLER K,et al. Fully bio-based epoxy thermoset based on epoxidized linseed oil and tannic acid[J]. Macromolecular Materials and Engineering,2022,307(12):2200455.
    [72]
    中华人民共和国工业和信息化部. 风力发电机组叶片用环氧结构胶粘剂:HG/T 5248—2017[S]. 北京:中国标准出版社,2017.
    [73]
    全国胶粘剂标准化技术委员会. 预制混凝土节段拼装用环氧胶粘剂:GB/T 44543—2024[S]. 北京:中国标准出版社,2024.
    [74]
    中华人民共和国工业和信息化部. 地基与基础处理用环氧树脂灌浆材料:JC/T 2379—2016[S]. 北京:中国标准出版社,2016.
    [75]
    中华人民共和国国家发展和改革委员会. 混凝土裂缝用环氧树脂灌浆材料:JC/T 1041—2007[S]. 北京:中国标准出版社,2007.
    [76]
    中华人民共和国工业和信息化部. 混凝土界面处理剂:JC/T 907—2018[S]. 北京:中国标准出版社,2018.
    [77]
    中华人民共和国住房和城乡建设部. 混凝土结构工程用锚固胶:JG/T 340—2011[S]. 北京:中国建筑工业出版社,2011.
    [78]
    中华人民共和国工业和信息化部. 环氧树脂灌注砂浆:JC/T 2630—2021[S]. 北京:中国标准出版社,2021.
    [79]
    杭州国电大坝安全工程有限公司. HK-EQ环氧胶泥:Q/GD DB 13—2017[S]. 杭州:杭州国电大坝安全工程有限公司,2017.
    [80]
    浙江省质量协会. 水性环氧地坪涂料:T/ZZB 3088—2023[S]. 杭州:浙江省质量协会,2023.
    [81]
    中华人民共和国工业和信息化部. 环氧磨石:JC/T 2748—2023[S]. 北京:中国标准出版社,2023.
    [82]
    国家标准化管理委员会. 树脂浇铸体性能试验方法:GB/T 2567—2021[S]. 北京:中国标准出版社,2021.
    [83]
    中国国家标准化管理委员会. 建筑防水涂料试验方法:GB/T 16777—2008[S]. 北京:中国标准出版社,2008.
    [84]
    中国国家标准化管理委员会. 塑料 环氧树脂 黏度测定方法:GB/T 22314—2008[S]. 北京:中国标准出版社,2008.
    [85]
    中国国家标准化管理委员会. 胶粘剂 拉伸剪切强度的测定(刚性材料对刚性材料):GB/T 7124—2008[S]. 北京:中国标准出版社,2008.
    [86]
    中华人民共和国化学工业部. 胶粘剂拉伸剪切蠕变性能试验方法(金属对金属):GB/T 7750—1987[S]. 北京:中国标准出版社,1987.
    [87]
    国家标准化管理委员会. 胶粘剂挥发性有机化合物限量:GB 33372—2020[S]. 北京:中国标准出版社,2020.
    [88]
    中华人民共和国住房和城乡建设部. 建筑砂浆基本性能试验方法标准:JGJ 1770—2009[S]. 北京:中国建筑工业出版社,2009.
    [89]
    中华人民共和国住房和城乡建设部. 工程结构加固材料安全性鉴定技术规范:GB 50728—2011[S]. 北京:中国建筑工业出版社,2011.
    [90]
    中华人民共和国航空工业部. 金属胶接结构胶粘剂规范:HB 5398—1988[S]. 北京:中国标准出版社,1988.
    [91]
    中华人民共和国水利部. 水工建筑物环氧树脂灌浆材料技术规范:SL/T 807—2021[S]. 北京:中国水利水电出版社,2021.
    [92]
    北京市住房和城乡建设委员会. 建筑工程用界面处理剂应用技术规程:DB 11/T346—2022[S]. 北京:中国标准出版社,2022.
    [93]
    中华人民共和国住房和城乡建设部. 混凝土结构加固设计规范:GB 50367—2013[S]. 北京:中国建筑工业出版社,2013.
    [94]
    国家能源局. 环氧树脂砂浆技术规程:DL/T 5193—2021[S]. 北京:中国电力出版社,2021.
    [95]
    国家能源局. 钢质管道液体环氧涂料内防腐技术规范:SY/T 0457—2019[S]. 北京:石油工业出版社,2019.
    [96]
    中华人民共和国住房和城乡建设部. 纤维增强复合材料工程应用技术标准:GB 50608—2020[S]. 北京:中国标准出版社,2020.
    [97]
    福建省地坪行业协会. 环氧磨石地坪施工及验收规范:T/FJFA 005—2022[S]. 福州:福建省地坪行业协会,2022.
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