Source Journal of Chinese Scientific and Technical Papers
Included as T2 Level in the High-Quality Science and Technology Journals in the Field of Architectural Science
Core Journal of RCCSE
Included in the CAS Content Collection
Included in the JST China
Indexed in World Journal Clout Index (WJCI) Report
Volume 56 Issue 4
Apr.  2026
Turn off MathJax
Article Contents
JIN Dian, ZHANG Wenjie. Remediation of Cr(VI)-Contaminated Soil by Reduction, Adsorption, and Solidification[J]. INDUSTRIAL CONSTRUCTION, 2026, 56(4): 217-224. doi: 10.3724/j.gyjzG23070416
Citation: JIN Dian, ZHANG Wenjie. Remediation of Cr(VI)-Contaminated Soil by Reduction, Adsorption, and Solidification[J]. INDUSTRIAL CONSTRUCTION, 2026, 56(4): 217-224. doi: 10.3724/j.gyjzG23070416

Remediation of Cr(VI)-Contaminated Soil by Reduction, Adsorption, and Solidification

doi: 10.3724/j.gyjzG23070416
  • Received Date: 2023-07-04
    Available Online: 2026-06-06
  • Publish Date: 2026-04-20
  • Among the two major states of chromium, Cr(VI) is high mobile and carcinogenic whereas Cr(III) is less toxic. Remediation of chromium-contaminated soil usually involves reducing Cr(VI) to Cr(III) and subsequently immobilizing it. In this paper, a combined remediation technique including reduction, adsorption, and solidification was proposed. By employing an adsorbent, the remediation effectiveness was improved and the amount of reducing and curing agent was to some extent decreased. Synthetic precipitation leaching procedure (SPLP), unconfined compressive strength (UCS), and acid neutralization capacity (ANC) tests were carried out to evaluate the remediation effect of different agent combinations and different addition procedures. SPLP tests showed that the reduction-adsorption-solidification treatment significantly reduced the leached chromium. Using calcium polysulfide as the reducing agent was more effective than using ferrous sulfate. UCS tests showed that the strength of the solidified soil was reduced after employing the adsorbent, but the standards for strength could still be satisfied. ANC tests demonstrated that the combined remediation technology improved the capacity of the solidified system to resist acid erosion. The best combined dosage was calcium polysulfide, vermiculite, and cement. The researches on adding procedures showed that adding the reducing agent and adsorbent together and then adding the curing agent achieved similar effects to adding the three agents separately. This could facilitate the remediation process.
  • loading
  • [1]
    GUO X Z,ZHANG W J,YU H S,et al. Reduction,stabilization,and solidification of Cr(VI)in contaminated soils with a sustainable by-product-based binder[J/OL]. Chemosphere,2022,307[2023-07-04]. https://doi.org/10.1016/j.chemosphere.2022.135902.
    [2]
    李喜林,赵雪,周启星,等. 废铁屑-改性粉煤灰联用处理铬渣渗滤液[J]. 环境工程学报,2016,10(6):2793-2799.
    [3]
    环境保护部,国土资源部. 全国土壤污染状况调查公报[J]. 国土资源通讯,2014(5):10-11.
    [4]
    CONNER J R,HOEFFNER S L. The history of stabilization/solidification technology[J]. Critical Reviews in Environmental Science and Technology,1998,28(4):325-396.
    [5]
    SINGH T S,PANT K K. Solidification/stabilization of arsenic containing solid wastes using portland cement,fly ash and polymeric materials[J]. Journal of Hazardous Materials,2006,131:29-36.
    [6]
    李喜林,张佳雯,陈冬琴,等. 水泥固化铬污染土强度及浸出试验研究[J]. 硅酸盐通报,2017,36(3):979-983.
    [7]
    WANG S,VIPULANANDAN C. Solidification/ stabilization of Cr(VI)with cement:leachability and XRD analyses[J]. Cement & Concrete Research,2000,30(3):385-389.
    [8]
    PARK J Y,KANG W H,HWANG I. Hexavalent chromium uptake and release in cement pastes[J]. Environmental Engineering Science,2006,23(1):133-140.
    [9]
    KAMESWARI K S B,NARASIMMAN L M,PEDABALLE V,et al. Diffusion and leachability index studies on stabilization of chromium contaminated soil using fly ash[J]. Journal of Hazardous Materials,2015,297:52-58.
    [10]
    BUERGE I J,HUG S J. Influence of mineral murfaces on chromium(VI)reduction by iron(II)[J]. Environmental Science and Technology,1999,33:4285-4291.
    [11]
    LI Y,LIANG J,HE X,et al. Kinetics and mechanisms of amorphous FeS2 induced Cr(VI)reduction[J]. Journal of Hazardous Materials,2016,320:216-225.
    [12]
    BUIU T U,OZVERDI A,ERDEM M. Leaching behavior of pollutants in ferrochrome arc furnace dust and its stabilization/solidification using ferrous sulphate and Portland cement[J]. Journal of Hazardous Materials,2009,162:893-898.
    [13]
    张文,杨勇,马泉智,等. 铬污染土壤还原-固化稳定化过程研究[J]. 环境工程,2014,32(增刊1):1028-1030.
    [14]
    MOON D H. Chromium leachability from S/S soils under modified semi-dynamic leaching conditions[J]. Environmental Engineering Research,2006,10(6):264-305.
    [15]
    HOU R J,WANG L W,SHEN Z T,et al. Simultaneous reduction and immobilization of Cr(VI)in seasonally frozen areas:Remediation mechanisms and the role of ageing[J/OL]. Journal of Hazardous Materials,2021,415[2023-07-04]. https://doi.org/10.1016/j.jhazmat.2021.125650.
    [16]
    BADAWY N A,EL-BAYAA A A,ALKHALIK E A. Vermiculite as an exchanger for copper(II)and Cr(III)ions,kinetic studies[J]. Ionics,2010,16(8):733-739.
    [17]
    KHAN S A,REHMAN U R,KHAN M A. Adsorption of chromium(III),chromium(VI)and silver(I)on bentonite[J]. Waste Management,1995,15(4):271-282.
    [18]
    MALANDRINO M,ABOLLINO O,BUOSO S,et al. Accumulation of heavy metals from contaminated soil to plants and evaluation of soil remediation by vermiculite[J]. Chemosphere,2011,82(2):169-178.
    [19]
    GAO J,WANG Y,YAN Y,et al. Protein extraction from excess sludge by alkali-thermal hydrolysis[J]. Environmental Science and Pollution Research,2020,27(10):8628-8637.
    [20]
    张亭亭,李江山,薛强,等. FeSO4稳定铬污染土的铬赋存形态及浸出特性研究[J]. 岩土力学,2019,40(12):4652-4658.
    [21]
    MONTANES M T,SANCHEZ R,ROUX M S. The effectiveness of the stabilization/solidification process on the leachability and toxicity of the tannery sludge chromium[J]. Journal of Environmental Management,2014,143:71-79.
    [22]
    BULUT U,OZVERDI A,ERDEM M. Leaching behavior of pollutants in ferrochrome arc furnace dust and its stabilization/solidification using ferrous sulphate and Portland cement[J]. Journal of Hazardous Materials,2009,162(2/3):893-898.
    [23]
    WAZNE M,MOON D H,JAGUPILLA S C,et al. Remediation of chromite ore processing residue using ferrous sulfate and calcium polysulfide[J]. Geosciences Journal,2007,11(2):105-110.
    [24]
    CHRYSOCHOOU M,FERREIRA D R,JOHNSTON C P. Calcium polysulfide treatment of Cr(VI)-contaminated soil[J]. Journal of Hazardous Materials,2010,179:650-657.
    [25]
    WAZNE M,JAGUPILLA S C,MOON D H,et al. Assessment of calcium polysulfide for the remediation of hexavalent chromium in chromite ore processing residue[J]. Journal of Hazardous Materials,2007,143:620-628.
    [26]
    高鑫,蒲一凡,朱静平,等. 天然蛭石吸附废水中Cr(VI)的动力学试验研究[J]. 非金属矿,2015,38(4):63-66.
    [27]
    STEGEMANN J A,COTE P L. A proposed protocol for evaluation of solidified wastes[J]. Science of the Total Environment,1996,178:103-110.
    [28]
    KOKSAL F,SAHIN Y,Gencel O. Influence of expanded vermiculite powder and silica fume on properties of foam concretes[J]. Construction and Building Materials,2020,257(1):116-124.
    [29]
    查甫生,刘晶晶,郝爱玲,等. NaCl侵蚀环境下水泥固化铅污染土强度及微观特性试验研究[J]. 岩石力学与工程学报,2015,34(增刊2):4325-4332.
    [30]
    United States Environmental Protection Agency. Prohibition on the disposal of bulk liquid hazardous waste in landfills-statutory interpretive guidance[S]. Washington,D. C.:United States Environmental Protection Agency,1996.
    [31]
    杜延军,金飞,刘松玉,等. 重金属工业污染场地固化/稳定处理研究进展[J]. 岩土力学,2011,32(1):116-124.
    [32]
    查甫生,许龙,崔可锐. 水泥固化重金属污染土的强度特性试验研究[J]. 岩土力学,2012,33(3):652-656.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (27) PDF downloads(0) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return