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YANG Ming, CHEN Yangli, WANG Yuanda, ZHANG Hongru, ZHANG Jingbo. Research on the Chloride Ion Diffusion Behavior and Modified Diffusion Model of Recycled Concrete with Varying Water-Cement Ratios and Recycled Coarse Aggregate Volume Fractions[J]. INDUSTRIAL CONSTRUCTION, 2025, 55(3): 245-254. doi: 10.3724/j.gyjz.G23092618
Citation: YANG Ming, CHEN Yangli, WANG Yuanda, ZHANG Hongru, ZHANG Jingbo. Research on the Chloride Ion Diffusion Behavior and Modified Diffusion Model of Recycled Concrete with Varying Water-Cement Ratios and Recycled Coarse Aggregate Volume Fractions[J]. INDUSTRIAL CONSTRUCTION, 2025, 55(3): 245-254. doi: 10.3724/j.gyjz.G23092618

Research on the Chloride Ion Diffusion Behavior and Modified Diffusion Model of Recycled Concrete with Varying Water-Cement Ratios and Recycled Coarse Aggregate Volume Fractions

doi: 10.3724/j.gyjz.G23092618
  • Received Date: 2023-09-26
    Available Online: 2025-06-07
  • Publish Date: 2025-03-20
  • The utilization of recycled aggregate (RA) in the production of recycled aggregate concrete (RAC) is a key method for reusing construction solid waste. However, compared to natural aggregate concrete (NAC), RAC exhibits poorer resistance to chloride ion (Cl-) ingress. This study aimed to investigate the distribution of Cl- in RAC under one-dimensional chloride ion diffusion, considering the influence of different water-cement ratios (w/c) and recycled aggregate volume fractions (VRCA). Fick’s second law was used to determine the Cl- diffusion coefficient of RAC.The time-varying models for the chloride ion diffusion coefficient considering the effects of w/c and VRCA were established, and the chloride ion concentration distribution models were modified accordingly. Microhardness testing was conducted to assess the effects of w/c and VRCA on the micro-mechanical properties of each meso-scale material phase, the thickness of the interfacial transition zone (ITZ) in RAC, and volume fractions of multiple material phases in RAC. The results indicated that an increase in w/c led to an increase in the Cl- diffusion coefficientof RAC, attributed to the thickening of the water film surrounding the aggregate, resulting in an increased thickness of ITZ1 and ITZ3. The enhancement effect of the interface transition zone on chloride ion transport was significant. Furthermore, as VRCA increased, the volume fraction of old aggregate volume increased, and the dilution effect and tortuosity effect became more pronounced compared to the interface transition zone effect, leading to a decrease in the Cl- diffusion coefficient with increasing VRCA.
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