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CAO Zhiyuan, NIU Ditao, LYU Yao. Numerical Simulation of Acid Gas Corroded Concrete in Industrial Environment[J]. INDUSTRIAL CONSTRUCTION, 2025, 55(1): 153-160. doi: 10.3724/j.gyjzG24100602
Citation: CAO Zhiyuan, NIU Ditao, LYU Yao. Numerical Simulation of Acid Gas Corroded Concrete in Industrial Environment[J]. INDUSTRIAL CONSTRUCTION, 2025, 55(1): 153-160. doi: 10.3724/j.gyjzG24100602

Numerical Simulation of Acid Gas Corroded Concrete in Industrial Environment

doi: 10.3724/j.gyjzG24100602
  • Received Date: 2024-10-06
    Available Online: 2025-03-28
  • The neutralization model of concrete corroded by CO2 and SO2 coupling was established. The model considered the dissolution process of solid calcium in concrete and the expansion damage caused by sulfation products. The influence of different water-cement ratios (0.37, 0.47, 0.57) on the neutralization process of concrete was studied. The changes of neutralization degree, gas diffusion coefficient, porosity, CaCO3 content and CaSO4 content of corroded concrete were analyzed. The results showed that with the increase of water-cement ratio, the diffusion range of CO2 gas in concrete gradually increased, while the diffusion range of SO2 was almost the same. After 28 days of corrosion, with the decrease of the water-cement ratio of concrete, the decrease in porosity of concrete increased gradually, and the expansion damage in concrete with different water-cement ratios was almost the same. In the area of increasing porosity, the change trends of concrete porosity were similar. With the increase of the water-cement ratio, the length of the complete sulfation area of concrete increased, the length of the partial sulfation area decreased, and the length of the partial carbonation area of concrete gradually increased.
  • [1]
    中华人民共和国国家统计局. 中国统计年鉴-能源消费总量[M]. 北京:中国统计出版社, 2019.
    [2]
    郑承煜.城市煤化工VOCs治理管控探索研究[J].中国煤炭,2019,45(9):68-72.
    [3]
    刘睿劼, 张智慧. 中国工业二氧化硫排放趋势及影响因素研究[J]. 环境污染与防治, 2012 (10): 100-104.
    [4]
    刘天恩,贺彦亮,靳盛,等. 防H2S和CO2酸性气体腐蚀水泥浆体系研究与应用 [J]. 钻井液与完井液, 2014, 31 (4): 68-70

    ,100.
    [5]
    崔伦涛. 锅炉金属腐蚀形态分析 [J]. 科技创新与应用, 2013(27): 105-106.
    [6]
    李月晨. 武汉钢铁工业区混凝土结构耐久性环境区划研究[D]. 西安:西安建筑科技大学, 2014.
    [7]
    张朋朋. 煤化工大气污染处理技术进展及发展方向[J]. 煤化工, 2019, 47(1):14-18.
    [8]
    牛荻涛,林明强,李月晨. 复杂化工环境混凝土腐蚀破坏机理分析[C]//全国第十三届混凝土结构基本理论及工程应用学术会议论文集. 南宁:2014:371-376.
    [9]
    申改燕,楚可嘉.传统煤化工无组织排放挥发性有机物的控制排放[J].化工进展,2017,36(增刊1):518-520.
    [10]
    曾贤刚,倪宏宏,陈果. 我国工业SO2排放趋势及影响因素分析[J]. 中国环保产业,2009(10):19-23.
    [11]
    PAVLIK V, BAJZA A, ROUSEKOUVA I, et a1. Degradation of concrete by flue gases from coal combustion[J]. Cem Concr Res, 2007, 37(7): 1085-1095.
    [12]
    SCHOLL E, KNOFEL D. On the effect of SO2 and CO2 on cement paste [J]. Cem. Concr. Res.,1991,2l(1):127-136.
    [13]
    王西明,张宏伟,吴丽娟.VOCs处理技术在煤制气项目的选用[J].煤炭加工与综合利用,2016(8):36-38,43.
    [14]
    BARY B, SELLIER A. Coupled moisture-carbon dioxide-calcium transfer model for carbonation of concrete [J]. Cem. Concr. Res., 2004, 34:1859-1872.
    [15]
    HANG X D, SUN W, YE C. Finite volume solution of heat and moisture transfer through three-dimensional textile materials [J]. Comput. Fluids., 2012, 57:25-39.
    [16]
    PAPADAKIS V G, VAYENAS C G, FARDIS M N. Physical and chemical characteristics affecting the durability of concrete [J]. ACI Mater J, 1991, 88:186-196.
    [17]
    THIERY M, VILLAIN G, DANGLA P, et al. Investigation of carbonation front shape on cementitious materials: Effect of the chemical kinetics[J]. Cem. Concr. Res., 2007, 37:1047-1058.
    [18]
    NEWSHAM K E, RUSHING J A, LASSWELL P M, et al. A comparative study of laboratory techniques for measuring capillary pressures in tight gas sands[C]//Proceedings of SPE Annual Technical Conference and Exhibition. Houston:2007.
    [19]
    Bouny V B, Mainguy, LASSABATERE M T. Characterization and identification of equilibrium and transfer moisture properties for ordinary and high-performance cementitious materials [J]. Cem. Concr. Res., 1999, 29:1225-1238.
    [20]
    ISGOR O B, RAZAQPUR A G. Finite element modeling of coupled heat transfer, moisture transport and carbonation processes in concrete structures [J]. Cem. Concr. Res., 2004, 26:57-73.
    [21]
    MUNTEAN A, BÖHMB M. A moving-boundary problem for concrete carbonation: Global existence and uniqueness of weak solutions [J]. J. Math. Anal. Appl., 2009, 350:234-251.
    [22]
    MUNTEAN A. On the interplay between fast reaction and slow diffusion in the concrete carbonation process: A matched-asymptotics approach [J]. Meccanica, 2009, 44:35-46.
    [23]
    PAPADAKIS V G, VAYENAS C G, FARDIS M N. Fundamental modeling and experimental investigation of concrete carbonation [J]. ACI Mater. J., 1991, 88:363-373.
    [24]
    牛荻涛,曹志远,吕瑶. 热湿环境下CO2-SO2耦合侵蚀水泥基材料的中性化机理及预测模型 [J]. 硅酸盐学报, 2024, 52 (2): 545-554.
    [25]
    BERNER U. A thermodynamic description of the evolution of the pore water chemistry and uranium speciation during the degradation of cement [R].Switzerland:N.P., 1990.
    [26]
    EUML R, TIXIER L, MOBASHER B. Modeling of damage in cement-based materials subjected to external sulfate attack. I: formulation [J]. J. Mater. Civil. Eng., 2003, 15:305-313.
    [27]
    SARKAR S, MAHADEVAN S, MEEUSSEN J, et al. Numerical simulation of cementitious materials degradation under external sulfate attack [J]. Ce. Concr. Comp., 2012, 32:241-252.
    [28]
    MAZARS J, CABOT G P. Continuum damage theory application to concrete [J]. J. Eng. Mech., 1989, 115:345-365.
    [29]
    吕瑶,牛荻涛,刘西光,等. 典型工业环境下混凝土硫化机理与预测模型 [J]. 建筑材料学报, 2022, 25 (6): 621-627

    ,634.
    [30]
    中华人民共和国住房和城乡建设部. 普通混凝土长期性能和耐久性试验方法标准: GB/T 50082—2009 [S]. 北京:中国标准出版社,2009.
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