Mechanism Study on Synergistic Effect of Microorganisms and Magnesium Oxide on Cementing Drill Cuttings
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摘要: 微生物诱导碳酸钙沉淀(MICP)是一种新型污染土加固修复方法,为钻屑的胶结处理提供了新思路。在分析高活性氧化镁凝胶材料胶结体的基础上,对微生物-氧化镁协同胶结钻屑进行了深入研究,提出了微生物与氧化镁协同胶结钻屑新方法。采用傅里叶变换红外吸收光谱仪、X射线衍射仪和扫描电子显微镜对胶结体进行测试,结果表明:微生物-氧化镁协同作用产物为玫瑰花状水菱镁石(4MgCO3·Mg(OH)2·4H2O)和针状三水碳镁石(MgCO3·3H2O);产物以致密的碳酸盐网络状结构将松散的颗粒胶结成结构完整的胶结体。对影响胶结体强度的因素分析表明:胶结体的强度发展趋势与微生物浓度、活性氧化镁浓度、养护时间成正相关,与含水量、尿素浓度呈负相关。Abstract: Microbial-induced calcium carbonate precipitation (MICP) is a new reinforcement and remediation method for contaminated soil, which also provides a new direction to cement drill cuttings. Based on the analysis of the cemented body of highly active magnesium oxide gel material, an in-depth study on synergistic cementation for drill cuttings by microorganisms and magnesium oxide was conducted, and a new treatment methods for drill cuttings was presented. The speciemens cemented by microorganisms combined with magenesium oxide were tested with FTIRs, XRDs and SEMs, and the results indicated that rosette hydro-magnesite (4MgCO3·Mg(OH)2·4H2O) and acicular nesquehonite (MgCO3·3H2O) were yielded in synergy of microorganism and magnesium oxide. The loose particles were cemented into the well-structured cemented body by the dense carbonate network which was the cementitious mechanism of the synergistic effect of microorganism and magnesium oxide. The analysis of the factors affecting the strength of the cured body showed that the development trend of the strength of the cured body was positively correlated with microbial concentrations, active magnesium oxide concentrations, and curing times, and negatively correlated with the water content and the urea concentration.
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Key words:
- microorganism /
- reactive magnesium oxide /
- synergy /
- cementation /
- drill cutting
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[1] 杨勇.中海油自研D+W工具在南海东部的首次应用分析[J].中国石油和化工标准与质量, 2020,40(4):120-121. [2] JÚNIOR I P, MARTINS A L, ATAÍDE C H, et al. Microwave drying remediation of petroleum-contaminated drill cuttings [J]. Journal of Environmental Management, 2017, 196: 659-665. [3] YAO G, CHEN Z, CHEN Q, et al. Behaviors of organic and heavy metallic pollutants during supercritical water oxidation of oil-Based drill cuttings [J/OL]. Water Air and Soil Pollution, 2018, 229(102)[2023-03-13]. https://doi.org/10.1007/s11270-018-3751-z. [4] ALAVI N, MESDAGHINIA A R, NADDAFI K, et al. Biodegradation of petroleum hydrocarbons in a soil polluted sample by oil-based drilling cuttings [J]. Soil and Sediment Contamination: An International Journal, 2014, 23(5): 586-597. [5] AL-ANSARY M S, AL-TABBAA A. Stabilization/solidification of synthetic petroleum drill cuttings [J]. Journal of Hazardous Materials, 2007, 141(2): 410-421. [6] MARTINEZ B C, DEJONG J T, GINN T R, et al. Experimental optimization of microbial-induced carbonate precipitation for soil improvement [J]. Journal of Geotechnical and Geoenvironmental Engineering, 2013, 139(4): 587-598. [7] SOON N W, LEE L M, KHUN T C, et al. Improvements in engineering properties of soils through microbial-induced calcite precipitation [J]. KSCE Journal of Civil Engineering, 2013, 17(4): 718-728. [8] ATASHGAHI S, TABARSA A, SHAHRYARI A, et al. Effect of carbonate precipitating bacteria on strength and hydraulic characteristics of loess soil[J]. Bulletin of Engineering Geology and the Environment, 2020, 79(9):4749-4763. [9] TANG G W, JIA C Q, WANG G H, et al. Role of Na-montmorillonite on microbially induced calcium carbonate precipitation [J/OL]. Molecules, 2021, 26(20) [2023-03-13]. https://doi.org/10.3390/molecules26206211. [10] TANG G W, HUANG F, WANG G H, et al. Valorization of water-based drill cuttings through the Bio-carbonation approach [J/OL]. Advances in Materials Science and Engineering, 2022[2023-03-13]. https://doi.org/10.1155/2022/3836863. [11] RUAN S, QIU J, WENG Y, et al. The use of microbial induced carbonate precipitation in healing cracks within reactive magnesia cement-based blends [J]. Cement and Concrete Research, 2019, 115: 176-188. [12] 黄涛, 方祥位, 张伟, 等. 活性氧化镁-微生物固化黄土试验研究[J]. 岩土力学, 2020, 41(17): 3300-3316. [13] YANG Y, RUAN S, WU S,et al. Biocarbonation of reactive magnesia for soil improvement[J/OL].Acta Geodaetica, 2020[2023-03-13]. https://doi.org/10.1007/s11440-020-01093-6. [14] KOLIAS S, GEORGIOU C. The effect of paste volume and of water content on the strength and water absorption of concrete [J]. Cement and Concrete Composites, 2005, 27(2): 211-216. [15] SHAH S J, SHROFF A V, PATEL J V, et al. Stabilization of fuel oil contaminated soil-A case study [J]. Geotechnical and Geological Engineering, 2003, 21(4): 415-427. [16] GE C, XUE D, YAO H. Microbial biomass, community diversity, and enzyme activities in response to urea application in tea orchard soils [J]. Communications in Soil Science and Plant Analysis, 2010, 41(7): 797-810.
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