EXPERIMENTAL STUDY ON PREPARATION AND MECHANICAL PROPERTIES OF MODIFIED MAGNESIUM PHOSPHATE CEMENT
-
摘要: 针对磷酸镁水泥凝结时间过快、施工性能差等问题,利用偏高岭土和空心玻璃微珠对其进行改性试验,研究偏高岭土和空心玻璃微珠对磷酸镁水泥强度、凝结时间及工作性能的影响。结果表明,氧化镁和磷酸二氢钾质量比在1~1.5时,随着偏高岭土掺量的增加,凝结时间逐步延长,强度有下降趋势,偏高岭土最佳掺量比为0.5~0.8;随着空心玻璃微珠掺量的增加,凝结时间有延长趋势,流动性显著提高,强度略有下降,最佳掺量为8%~12%。最终制备的磷酸镁水泥凝结时间可控、强度可靠,且表观密度较低,满足加固材料要求。Abstract: In order to solve the problems of fast setting time and poor operability of magnesium phosphate cement, metakaolin and hollow glass microbeads were used to modify the cement, and magnesium phosphate cement with properties of reinforcement material was prepared. The influence of metakaolin and hollow glass microbeads on cement strength, setting time and working performance were studied. The results showed that when the mass ratio of magnesium oxide and potassium dihydrogen phosphate was 1-1.5, the setting time gradually lengthens and the strength declined as the content of metakaolin increased. The content of metakaolin should be 0.5-0.8. With the increase of the content of hollow glass microbeads, the setting time tended to prolong, the fluidity increased significantly and the strength decreased slightly. The optimal content of hollow glass microbeads was 0.08-0.12. The magnesium phosphate cement prepared had controllable setting time, reliable strength, and low apparent density, which could meet the requirements of reinforcement materials.
-
Key words:
- magnesium phosphate cement /
- metakaolin /
- hollow glass-bead /
- workability /
- mechanical properties
-
[1] 方圆,陈兵.玻璃纤维对磷酸镁水泥砂浆力学性能的增强作用及机理[J].材料导报B(研究篇),2017,31(12):6-9. [2] FANG Y, CHEN B, ODERJI S Y. Experimental Research on Magnesium Phosphate Cement Mortar Reinforced by Glass Fiber[J]. Construction and Building Materials, 2018, 188:729-736. [3] 姜自超,齐召庆.纤维对磷酸镁水泥性能的影响试验研究[J].当代化工,2017,46(2):215-218. [4] 林挺伟.纤维增强磷酸钾镁水泥砂浆力学性能研究[J].福州大学学报(自然科学版),2017,45(4):528-534. [5] FENG H, SHEIKH M N, HADI M N S, et al. Interface Bond Performance of Steel Fibre Embedded in Magnesium Phosphate Cementitious Composite[J]. Construction and Building Materials, 2018,185:648-660. [6] FENG H, SHEIKH M N, HADI M N S, et al. Mechanical Properties of Micro-Steel Fibre Reinforced Magnesium Potassium Phosphate Cement Composite[J]. Construction and Building Materials, 2018, 185:423-435. [7] 赵江涛,李相国,张琰,等.粉煤灰对磷酸镁水泥的影响[J].硅酸盐通报,2018,37(2):695-700. [8] 李国新,仝万亮,张歌,等.粉煤灰和矿粉对磷酸镁水泥性能的影响[J].硅酸盐通报,2016,35(2):352-357. [9] 曾翠云,万德刚,董峰亮,等.粉煤灰改性磷酸镁水泥耐久性能的试验研究[J].粉煤灰综合利用,2016(3):27-30. [10] XU B W, LOTHENBACH B, MA H Y. Properties of Fly Ash Blended Magnesium Potassium Phosphate Mortars:Effect of the Ratio Between Fly Ash and Magnesia[J]. Cement and Concrete Composites, 2018, 90:169-177. [11] ZHENG D D, JI T, WANG C Q, et al. Effect of the Combination of Fly Ash and Silica Fume on Water Resistance of Magnesium-Potassium Phosphate Cement[J]. Construction and Building Materials, 2016, 106:415-421. [12] GARDNER L J, BERNAL S A, WALLING S A, et al. Characterization of Magnesium Potassium Phosphate Cements Blended with Fly Ash and Ground Granulated Blast Furnace Slag[J]. Cement and Concrete Research, 2015, 74:78-87. [13] LIAO W Y, MA H Y, SUN H F, et al. Potential Large-Volume Beneficial Use of Low-Grade Fly Ash in Magnesia Phosphate Cement Based Materials[J]. Fuel, 2017, 209:490-497. [14] MO L W, LYU L M, DENG M, et al. Influence of Fly Ash and Metakaolin on the Microstructure and Compressive Strength of Magnesium Potassium Phosphate Cement Paste[J]. Cement and Concrete Research, 2018, 111:116-129. [15] CHONG L L, SHI C J, YANG J M, et al. Effect of Limestone Powder on the Water Stability of Magnesium Phosphate Cement-Based Materials[J]. Construction and Building Materials, 2017, 148:590-598. [16] SHI C J, YANG J M, YANG N, et al. Effect of Waterglass on Water Stability of Potassium Magnesium Phosphate Cement Paste[J]. Cement and Concrete Composites, 2014, 53:83-87. [17] 王会新,戴磊,张倩倩.钢铁渣粉改性磷酸镁水泥的研究[J].建筑技术,2017,48(10):1042-1044. [18] 吴凯,叶钰燕,施惠生,等.钢渣对磷酸盐水泥基材料性能的影响机制[J].同济大学学报,2018,46(1):87-93. [19] 石亚文,陈兵.偏高岭土改性磷酸镁水泥[J].硅酸盐学报,2018,46(8):1111-1116. [20] LU X, CHEN B. Experimental Study of Magnesium Phosphate Cements Modified by Metakaolin[J]. Construction and Building Materials, 2016, 123:719-726. [21] LU Z Y, HOU D S, MA H Y, et al. Effects of Graphene Oxide on the Properties and Microstructures of the Magnesium Potassium Phosphate Cement Paste[J]. Construction and Building Materials, 2016, 119:107-112.
点击查看大图
计量
- 文章访问数: 104
- HTML全文浏览量: 10
- PDF下载量: 3
- 被引次数: 0