EFFECT OF CURING REGIMES ON CHLORIDION PENETRATION OF WHITE HIGH-STRENGTH CONCRETE
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摘要: 通过快速氯离子扩散系数法研究了不同养护方式对白色混凝土抗氯离子渗透性能的影响。结果表明:纯白水泥混凝土在三组养护方式中抗氯离子渗透性最差,使用矿物掺合料可大幅度降低白水泥混凝土的快速氯离子扩散系数(DRCM);标准养护下混凝土的DRCM最低,匹配养护较高,蒸汽养护最高;白水泥早期水化剧烈,第二放热峰出现时间最早,峰值最高,但累积放热量次于普通水泥;纯白水泥混凝土绝热温升最终温度最高,水泥-矿粉体系混凝土次之,水泥-矿粉-石灰石粉最低;经孔结构分析可知,蒸汽养护虽可激发混凝土水化进程,降低孔隙率,但会促使孔结构往粗孔方向发展,平均孔径增大。Abstract: The rapid chloridion diffusion coefficient method was used to study the effect of different curing regimes and the use of mineral admixture on chloridion resistance of white concrete. The results showed that the pure white cement concrete had the lowest resistance to chloridion penetration among the three groups of curing regimes. The use of mineral admixtures could greatly reduce the rapid chloridion diffusion coefficient (DRCM) of the white cement concrete; the DRCM of the concrete under standard curing was the lowest, the value of matching curing was the second high and that of steam curing was the highest; the second exothermic peak of white cement hydration in the early stage appeared earliest, and its peak was the highest data. However, the cumulative heat release of pure white cement was lower than that of ordinary cement. In addition, the pure white cement concrete had the highest adiabatic temperature rise (ATR) and the highest temperature, the concrete with cement-mineral powder system possessed the second-high ATR and the concrete with cement-mineral powder-limestone powder had the lowest value. Through the pore structure analysis, it could be seen that although steam curing might stimulate the hydration process of the concrete and reduce the porosity, it would promote the pore structure to develop toward the rough pore and would increase the average pore diameter.
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[1] 王波,初俊青,宋远明. 贝壳基生态复合白水泥制备及性能研究[J]. 建筑材料学报, 2012, 15(5):670-673. [2] 侯贵华,许仲梓. 白色阿利尼特水泥的形成及其矿物相研究[J]. 硅酸盐学报, 2003(5):508-512. [3] 黎恒杆,王玉林,罗昊,等. 多壁碳纳米管白水泥复合材料力学性能与电学性能试验研究[J]. 硅酸盐通报, 2019, 38(9):2808-2813. [4] 张桂雪,严云,胡志华,等. 具有光催化性能的水泥基掺和料的制备[J]. 非金属矿, 2016, 39(4):38-42. [5] ZHANG A, GE Y, YANG W, et al. Comparative Study on the Effects of Nano-SiO2, Nano-Fe2O3 and Nano-NiO on Hydration and Microscopic Properties of White Cement[J]. Construction and Building Materials, 2019, 228:DOI: 10.1016/j.conbuildmat.2019.116767. [6] HOSSEINI P, ASCE S M, ABOLHASANI M, et al. Influence of Two Types of Nanosilica Hydrosols on Short-Term Properties of Sustainable White Portland Cement Mortar[J]. Journal of Materials in Civil Engineering, 2017, 30(2):1-11. [7] COLORADO H A, GARCIA E, BUCHELY M F. White Ordinary Portland Cement Blended with Superfine Steel Dust with High Zinc Oxide Contents[J]. Construction and Building Materials, 2016, 112:816-824. [8] HAMAD B S. Investigations of Chemical and Physical Properties of White Cement Concrete[J]. Advanced Cement Based Materials, 1995, 2(4):161-167. [9] GUTIÉRREZ J C R, BAENA O J R, TOBÓN J I. Evaluation of White Cement Coloured with Ultramarine Blue Pigment[J]. Dyna, 2009, 76(157):225-231. [10] 彭波. 蒸养制度对高强混凝土性能的影响[D]. 武汉:武汉理工大学, 2007. [11] 阎培渝,崔强. 养护制度对高强混凝土强度发展规律的影响[J]. 硅酸盐学报, 2015, 43(2):133-137. [12] 史才军,王德辉,贾煌飞,等. 石灰石粉在水泥基材料中的作用及对其耐久性的影响[J]. 硅酸盐学报, 2017, 45(11):1582-1593. [13] 朱街禄,宋军伟,王露,等. 铜渣粉-水泥复合胶凝体系的水化热及动力学研究[J]. 建筑材料学报,2019,23(6):1282-1288. [14] 石梦晓. 镍铁渣粉在水泥基复合胶凝材料中的作用机理[D]. 北京:清华大学, 2017. [15] KRSTULOVIĆ R, DABIĆ P. A Conceptual Model of the Cement Hydration Process[J]. Cement and Concrete Research, 2000, 30(5):693-698.
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