RESEARCH ON MECHANICAL PROPERTIES OF CEMENT-BASED COMPOSITES REINFORCED WITH NANO GRAPHENE OXIDE
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摘要: 氧化石墨烯纳米片(GONPs)具有独特的物理性质,使其在水泥基体中成为有效的增强材料。通过试验,研究不同GONPs掺量对水泥基复合材料力学性能、孔径分布及微观结构特征的影响。GONPs以水泥质量分数为0%,0.01%,0.02%,0.03%,0.04%,0.05%制备水泥基复合材料,对经28 d养护的试块进行了抗压强度和间接抗拉强度测试、热重分析(TGA)与X射线衍射分析;利用氮气吸附技术研究试样断裂表面的孔径分布并通过扫描电镜(SEM)观察其微观结构。研究结果表明:通过将GONPs掺入水泥基复合材料中,最高可使其抗压强度和间接抗拉强度分别提高13.1%和41.3%。GONPs与普通硅酸盐水泥(OPC)的结合显著降低了水泥砂浆的孔隙数量,使其微观结构得到显著改善,同时会在水泥砂浆内部形成大量排列规整的片状及花瓣状晶体,提高了水泥基复合材料的力学性能。Abstract: Graphene oxide nanosheets (GONPs) have unique physical properties, making them effective reinforcing materials. The effects of different amounts of GONPs on the mechanical properties, pore size distribution and microstructure characteristics of cement-based composites were studied in this paper. GONPs prepared cement-based composites at 0%, 0.01%, 0.02%, 0.03%, 0.04%, and 0.05% of the cement mass fraction. The compressive strength and indirect tensile strength of the samples were measured at the 28-day age, as well as thermogravimetric analysis (TGA) and X-ray diffraction analysis; nitrogen adsorption technique was used to study the pore size distribution of the fracture surface of the sample and the microstructure was observed by scanning electron microscopy (SEM). The results showed that by incorporating GONPs into cement-based composites, the maximum compressive strength and indirect tensile strength could be increased by 13% and 41%, respectively. The combination of GONPs and ordinary Portland cement (OPC) significantly reduced the pore size of cement mortar, significantly improved its microstructure, and improved the mechanical properties of cement-based composites.
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