杂散电流环境下保护层内氯盐传输特性研究
doi: 10.13204/j.gyjz201406017
STUDY OF PROPERTIES OF CHLORIDE IONS TRANSPORTATION IN CONCRETE COVER UNDER THE STRAY CURRENTS ENVIRONMENT
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摘要: 采用电迁移锈蚀法对杂散电流环境下混凝土保护层中氯盐传输特性进行了研究。通过对四组试件在不同电流强度,不同通电时间情况下混凝土保护层内氯离子浓度的变化特征,重点分析了电场作用对保护层内氯离子传输进程和试件表面氯离子浓度的影响规律。结果表明,电场作用下保护层内氯离子浓度在数十小时内便从非稳态传输演变为稳态传输,传输效率较自由扩散高900多倍,但在稳态传输阶段氯离子浓度并非稳定不变,而是随通电时间增加整体呈下降趋势;保护层内氯离子达稳态传输前,混凝土表面氯离子浓度增长规律与一般氯盐环境中明显不同,其随通电时间增长以幂函数形式降低,随电流强度增加呈幂函数形式增长,且受通电时间的影响更为显著。Abstract: Based on the corrosion method of electricity migration,the characteristics of the chloride ion transmission under the stray current environment in the concrete cover were researched. Through four groups of specimens,the variation characteristics of the chloride ion concentration in concrete cover in the case of different current intensity and power-on time were researched in the test. This paper mainly analyzed the influence rules of chloride ion transmission in concrete cover and the chloride concentration on concrete surface under the action of electric field. The results showed that the chloride ion concentration in concrete cover evolved from non-steady-state transmission to steady-state transmission in several hours under the action of the electric field. Its transmission efficiency was 900 times higher than the free diffusion results. But the chloride ion concentration dropped with the increase of power-on time,not stable in the steady-state transmission stage. The growth rules of the concrete surface chloride ion concentration were significantly different from general chloride environment before the chloride ion concentration in concrete cover turn to steady-state transmission. It dropped in power function with the increase of the power-on time,growed in power function with the increase of the current intensity. And the power-on time is the more important factor.
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